Is it safe to use silicone grease with Nitrox?

The short answer is NO. The longer answer is it depends on the exact product formulation and gas pressure but as a practical matter the answer is still no. Silicone "grease" is a generic term for a variety of lubricant formulations that are based on some form of pure silicone oil, most commonly polydimethylsiloxane (PDMS). While pure PDMS itself is a chemically inert inorganic substance that is not combustible; in order to make the little tub or spray can of generic 'scuba lube', the PDMS is mixed with thickeners and/or organic solvents that typically are readily combustible. Lubricant contamination in high pressure compressed gas equipment is a frequent cause of oxygen fires. In general, lubrication in oxygen service applications should be avoided whenever possible. Oxygen service applications in SCUBA that require lubrication must use specialized (and relatively expensive) lubricants, typically based on polytetrafluoroethylene (PTFE) or polychlorotrifluoroethylene (PCTFE) compounds.

It is true that in low pressure Nitrox applications such as regulator second stages and rebreather loops, the type of lubricant is pretty much irrelevant to oxygen fire safety. Occasionally, the desire to minimize use of expensive oxygen compatible lubricants can lead to the erroneous assumption that inexpensive silicone lubricants might used in ambient or low pressure applications that are in close proximity to high pressure applications. However, the high tack and adhesion property of silicone lubes also makes them very migratory and difficult to completely remove. In practice, we find silicone lubrication on the low pressure side of equipment will eventually be transferred to the high pressure side such as a first stage connector or valve outlet. Never use silicone lubricants with electrical contacts, even though this is an often suggested practice. Silicone products will react with plastics and other contaminates to form insulating films and silicone carbide compounds which can cause intermittent connections in low-current applications such as rebreather oxygen sensors. When multiple lubricants are available, there is also the very real increased risk of inadvertently applying the wrong lubricant. In practice, if lubrication is required it is best to only use oxygen compatible lubricant consistently throughout all equipment in service with Nitrox regardless of pressure.

Dive Gear Express avoids silicone lubricants in our facility, using only oxygen compatible lubricants for all SCUBA applications that require lubrication. Any products we identify as Nitrox Ready or Oxygen Service will meet industry standards for both oxygen compatibility and oxygen cleanliness prior to initial use.

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